Inorganic Chemistry – James E. House – 1ra Edición

I. STRUCTURE OF ATOMS AND MOLECULES

1. Light, Waves, and Atoms

1.1 Some Early Experiments in Atomic Physics

1.2 The Nature of Light

1.3 The Bohr Model

1.4 Particle-Wave Duality

1.5 Electronic Properties of Atoms

1.6 Nuclear Binding Energy

1.7 Nuclear Stability

1.8 Types of Nuclear Decay

1.9 Predicting Decay Modes

2. Basic Quantum Mechanics and Atomic Structure

2.1 The Postulates

2.2 The Hydrogen Atom

2.3 The Helium Atom

2.4 Slater Wave Functions

2.5 Electron Configurations

2.6 Spectroscopic States

3. Covalent Bonding in Diatomic Molecules

3.1 The Basic Ideas of Molecular Orbital Methods

3.2 The H2+ and H2 Molecules

3.3 Diatomic Molecules of Second Row Elements

3.4 Photoelectron Spectroscopy

3.5 Heteronuclear Diatomic Molecules

3.6 Electronegativity

3.7 Spectroscopic States for Diatomic Molecules

4. A Survey of Inorganic Structure and Bonding

4.1 Structures of Molecules Having Single Bonds

4.2 Resonance and Formal Charge

4.3 Complex Structures;A Preview of Coming Attractions

4.4 Electron Deficient Molecules

4.5 Structures Having Unsaturated Rings

4.6 Bond Energies

5. Symmetry and Molecular Orbitals

5.1 Symmetry Elements

5.2 Orbital Symmetry

5.3 A Brief Look at Group Theory

5.4 Construction of Molecular Orbitals

5.5 Orbitals and Angles

5.5 Simple Calculations Using the Hückel Method

II. CONDENSED PHASES

6. Intermolecular Interactions

6.1 Dipole Moments

6.2 Dipole-Dipole Forces

6.3 Dipole-Induced Dipole Forces

6.4 London (Dispersion) Forces

6.5 van der Waals Equation

6.6 Hydrogen Bonding

6.7 Cohesion Energy and Solubility Parameters

7. Ionic Bonding and Structures of Solids

7.1 Energetics of Crystal Formation

7.2 Madelung Constants

7.3 The Kapustinskii Equation

7.4 Ionic Sizes and Crystal Environment

7.5 Crystal Structures

7.6 Solubility of Ionic Compounds

7.7 Proton and Electron Affinities

7.8 Structures of Metals

7.9 Defects in Crystals

7.10 Phase Transitions in Solids

7.11 Heat Capacity

7.12 Hardness of Solids

8. Dynamic Processes in Inorganic Solids

8.1 Characteristics of Solid State Reactions

8.2 Kinetic Models for Reactions in Solids

8.3 Thermal Methods of Analysis

8.4 Effects of Pressure

8.5 Reactions in Some Solid Inorganic Compounds

8.6 Phase Transitions

8.7 Reactions at Interfaces

8.8 Diffusion in Solids

8.9 Sintering

8.10 Drift and Conductivity

III. ACIDS, BASES, AND SOLVENTS

9. Acid-Base Chemistry

9.1 Arrhenius Theory

9.2 Brønsted-Lowry Theory

9.3 Factors Affecting Strength of Acids and Bases

9.4 Acid-Base Character of Oxides

9.5 Proton Affinities

9.6 Lewis Theory

9.7 Catalytic Behavior of Acids and Bases

9.8 The Hard-Soft Interaction Principle

9.9 Electronic Polarizabilities

9.10 The Drago Four-Parameter Equation

10. Chemistry in Nonaqueous Solvent

10.1 Some Common Nonaqueous Solvents

10.2 The Solvent Concept

10.3 Amphoteric Behavior

10.4 The Coordination Model

10.5 Chemistry in Liquid Ammonia

10.6 Liquid HF

10.7 Liquid Sulfur Dioxide

10.8 Superacids

IV. CHEMISTRY OF THE ELEMENTS

11. Chemistry of Metallic Elements

11.1 The Metallic Elements

11.2 Band Theory

11.3 Groups IA and IIA

11.4 Zintl Phases

11.5 Chemistry of Aluminum and Beryllium

11.6 First Row Transition Metals

11.7 Second and Third Row Transition Metals

11.8 Alloys

11.9 Chemistry of Transition Metals

11.10 Lanthanides

12. Organometallic Compounds of Main Group Metals

12.1 Preparation of Organometallic Compounds

12.2 Organometallic Compounds of Group IA Metals

12.3 Organometallic Compounds of Group IIA Metals

12.4 Organometallic Compounds of Group IIIA Metals

12.5 Organometallic Compounds of Group IVA Metals

12.6 Organometallic Compounds of Group VA Elements

12.7 Organometallic Compounds of Zn, Cd, and Hg

13. Chemistry of Nonmetallic Elements I. Hydrogen, Boron, Oxygen and Carbon

13.1 Hydrogen

13.2 Boron

13.3 Oxygen

13.4 Carbon

14. Chemistry of Nonmetallic Elements II.

14.1 Silicon, Germanium, Tin, and Lead

14.2 Nitrogen

14.3 Phosphorus, Arsenic, and Antimony

15. Chemistry of Nonmetallic Elements III. Groups VIA-VIIIA

15.1 Sulfur, Selenium, and Tellurium

15.2 Halogens

15.3 Noble Gases

V. CHEMISTRY OF COORDINATION COMPOUNDS

Introduction to Coordination Chemistry

16.1 Structures of Coordination Compounds

16.2 Metal-Ligand Bonds

16.3 Naming Coordination Compounds

16.4 Isomerism

16.5 A Simple Valence Bond Description of Coordinate Bonds

16.6 Magnetism

16.7 A Survey of Complexes of First Row Metals

16.8 Complexes of Second and Third Row Metals

16.9 The 18-Electron Rule

16.10 Back Donation

16.11 Complexes of Dinitrogen, Dioxygen, and Dihydrogen

Ligand Fields and Molecular Orbitals

17.1 Splitting of d Orbital Energies in Octahedral Fields

17.2. Splitting of d Orbital Energies in Fields of Other Symmetry

17.3 Factors Affecting 

17.4 Consequences of Crystal Field Splitting

17.5 Jahn-Teller Distortion

17.6 Spectral Bands

17.7 Molecular Orbitals in Complexes

Interpretation of Spectra

18.1 State Splitting

18.2 Orgel Diagrams

18.3 Quantitative Methods

18.4 Racah Parameters

18.5 The Nephelauxetic Effect

18.6 Tanabe-Sugano Diagrams

18.7 The Lever Method

18.8 Jørgensen's Method

18.9 Charge Transfer Absorption

Composition and Stability of Complexes

19.1 Composition of Complexes in Solution

19.2 Job's Method of Continuous Variations

19.3 Equilibria Involving Complexes

19.4 Distribution Diagrams

19.5 Factors Affecting the Stability of Complexes

Synthesis and Reactions of Coordination Compounds

20.1 Synthesis of Coordination Compounds

20.2 Substitution in Octahedral Complexes

20.3 Crystal Field Effects

20.4 Acid Catalyzed Reactions of Complexes

20.5 Base Catalyzed Reactions of Complexes

20.6 The Compensation Effect

20.7 Linkage Isomerization

20.8 Substitution in Square Planar Complexes

20.9 The Trans Effect

20.10 Electron Transfer Reactions

20.11 Reactions in Solid Coordination Compounds

Complexes Containing Metal-Carbon and Metal-Metal Bonds

21.1 Binary Metal Carbonyls

21.2 Structures of Metal Carbonyls

21.3 Bonding of Carbon Monoxide to Metals

21.4 Preparation of Metal Carbonyls

21.5 Reactions of Metal Carbonyls

21.6 Structure and Bonding in Metal-Alkene Complexes

21.7 Preparation of Metal Alkene Complexes

21.8 Chemistry of Cyclopentadienyl and Related Complexes

21.9 Reactions of Ferrocene and Other Metallocenes

21.10 Complexes of Benzene and Related Aromatics

21.11 Compounds Containing Metal-Metal Bonds

21.12 Carbonyl Hydrides

Coordination Compounds in Catalysis and Biochemistry

22.1 Elementary Steps in Catalysis

22.2 Homogeneous Catalysis

22.3 Bioinorganic chemistry.