Chemistry: The Molecular Nature of Matter and Change with Advanced Topics – Martin S. Silberberg, Patricia Amateis – 7th Edition

Chapter 1. Keys to the Study of Chemistry
1.1. Some Fundamental Definitions (18)
1.2. Chemical Arts and the Origins of Modern Chemistry (1)
1.3. The Scientific Approach. Developing a Model (1)
1.4. Measurement in Scientific Study (70)
1.5. Uncertainty in Measurement. Significant Figures (26)
1. Comprehensive Problems (35)
1. Follow-Up Problems (8)
1. Chemical Connections
1. Test Bank (68)
1. Extra Problems (3)
1. WebAssign Answer Entry Tutorials (1)

Chapter 2. The Components of Matter
2.1. Elements, Compounds, and Mixtures. An Atomic Overview (17)
2.2. The Observations That Led to an Atomic View of Matter (9)
2.3. Dalton's Atomic Theory
2.4. The Observations That Led to the Nuclear Atom Model
2.5. The Atomic Theory Today (8)
2.6. Elements. A First Look at the Periodic Table (33)
2.7. Compounds. Introduction to Bonding (21)
2.8. Compounds. Formulas, Names, and Masses (78)
2.9. Mixtures. Classification and Separation (2)
2. Comprehensive Problems (33)
2. Follow-Up Problems (16)
2. Chemical Connections
2. Test Bank (89)
2. Extra Problems (6)
2. WebAssign Answer Entry Tutorials (1)

Chapter 3. Stoichiometry of Formulas and Equations
3.1. The Mole (41)
3.2. Determining the Formula of an Unknown Compound (33)
3.3. Writing and Balancing Chemical Equations (23)
3.4. Calculating Quantities of Reactant and Product (44)
3. Comprehensive Problems (22)
3. Follow-Up Problems (15)
3. Chemical Connections
3. Test Bank (97)
3. Extra Problems (10)
3. WebAssign Answer Entry Tutorials

Chapter 4. Three Major Classes of Chemical Reactions
4.1. Solution Concentration and the Role of Water as a Solvent (29)
4.2. Writing Equations for Aqueous Ionic Reactions
4.3. Precipitation Reactions (22)
4.4. Acid-Base Reactions (26)
4.5. Oxidation-Reduction (Redox) Reactions (31)
4.6. Elements in Redox Reactions (14)
4.7. The Reversibility of Reactions and the Equilibrium State (2)
4. Comprehensive Problems (15)
4. Follow-Up Problems (8)
4. Chemical Connections
4. Test Bank (96)
4. Extra Problems (8)
4. WebAssign Answer Entry Tutorials

Chapter 5. Gases and the Kinetic-Molecular Theory
5.1. An Overview of the Physical States of Matter
5.2. Gas Pressure and Its Measurement (21)
5.3. The Gas Laws and Their Experimental Foundations (61)
5.4. Rearrangements of the Ideal Gas Law (37)
5.5. The Kinetic-Molecular Theory. A Model for Gas Behavior (33)
5.6. Real Gases. Deviations from Ideal Behavior (8)
5. Comprehensive Problems (21)
5. Follow-Up Problems (12)
5. Chemical Connections (1)
5. Test Bank (98)
5. Extra Problems (6)
5. WebAssign Answer Entry Tutorials

Chapter 6. Thermochemistry. Energy Flow and Chemical Change
6.1. Forms of Energy and Their Interconversion (46)
6.2. Enthalpy. Changes at Constant Pressure (36)
6.3. Calorimetry. Measuring the Heat of a Chemical or Physical Change (21)
6.4. Stoichiometry of Thermochemical Equations (34)
6.5. Hess's Law. Finding ? H of Any Reaction (33)
6.6. Standard Enthalpies of Reaction (?H°rxn) (14)
6. Comprehensive Problems (6)
6. Follow-Up Problems (9)
6. Chemical Connections (1)
6. Test Bank (74)
6. Extra Problems (5)
6. WebAssign Answer Entry Tutorials

Chapter 7. Quantum Theory and Atomic Structure
7.1. The Nature of Light (9)
7.2. Atomic Spectra (7)
7.3. The Wave-Particle Duality of Matter and Energy (5)
7.4. The Quantum-Mechanical Model of the Atom (2)
7. Comprehensive Problems (30)
7. Follow-Up Problems (7)
7. Chemical Connections (1)
7. Test Bank (72)
7. Extra Problems (3)
7. WebAssign Answer Entry Tutorials

Chapter 8. Electron Configuration and Chemical Periodicity
8.1. Characteristics of Many-Electron Atoms (29)
8.2. The Quantum-Mechanical Model and the Periodic Table (37)
8.3. Trends in Three Atomic Properties (29)
8.4. Atomic Properties and Chemical Reactivity (77)
8. Comprehensive Problems (46)
8. Follow-Up Problems (8)
8. Chemical Connections
8. Test Bank (70)
8. Extra Problems (1)
8. WebAssign Answer Entry Tutorials

Chapter 9. Models of Chemical Bonding
9.1. Atomic Properties and Chemical Bonds (35)
9.2. The Ionic Bonding Model (30)
9.3. The Covalent Bonding Model (29)
9.4. Bond Energy and Chemical Change (1)
9.5. Between the Extremes. Electronegativity and Bond Polarity (18)
9.6. An Introduction to Metallic Bonding (1)
9. Comprehensive Problems (4)
9. Follow-Up Problems (3)
9. Chemical Connections
9. Test Bank (66)
9. Extra Problems (1)
9. WebAssign Answer Entry Tutorials (1)

Chapter 10. The Shapes of Molecules
10.1. Depicting Molecules and Ions with Lewis Structures (43)
10.2. Valence-Shell Electron-Pair Repulsion (VSEPR) Theory (36)
10.3. Molecular Shape and Molecular Polarity (6)
10. Comprehensive Problems (12)
10. Follow-Up Problems (8)
10. Chemical Connections
10. Test Bank (87)
10. Extra Problems (6)
10. WebAssign Answer Entry Tutorials

Chapter 11. Theories of Covalent Bonding
11.1. Valence Bond (VB) Theory and Orbital Hybridization (42)
11.2. Modes of Orbital Overlap and the Types of Covalent Bonds (3)
11.3. Molecular Orbital (MO) Theory and Electron Delocalization (32)
11. Comprehensive Problems (5)
11. Follow-Up Problems (4)
11. Chemical Connections
11. Test Bank (46)
11. Extra Problems (3)
11. WebAssign Answer Entry Tutorials

Chapter 12. Intermolecular Forces. Liquids, Solids, and Phase Changes
12.1. An Overview of Physical States and Phase Changes (2)
12.2. Quantitative Aspects of Phase Changes (14)
12.3. Types of Intermolecular Forces (32)
12.4. Properties of the Liquid State (32)
12.5. The Uniqueness of Water
12.6. The Solid State. Structure, Properties, and Bonding (52)
12.7. Advanced Materials (2)
12. Comprehensive Problems (8)
12. Follow-Up Problems (4)
12. Chemical Connections
12. Test Bank (93)
12. Extra Problems (1)
12. WebAssign Answer Entry Tutorials

Chapter 13. The Properties of Mixtures. Solutions and Colloids
13.1. Types of Solutions. Intermolecular Forces and Solubility (2)
13.2. Intermolecular Forces and Biological Macromolecules
13.3. Why Substances Dissolve. Understanding the Solution Process (4)
13.4. Solubility as an Equilibrium Process (9)
13.5. Concentration Terms (16)
13.6. Colligative Properties of Solutions (105)
13.7. The Structure and Properties of Colloids
13. Comprehensive Problems (8)
13. Follow-Up Problems (9)
13. Chemical Connections (1)
13. Test Bank (91)
13. Extra Problems (1)
13. WebAssign Answer Entry Tutorials

Chapter 14. Periodic Patterns in the Main-Group Elements
14.1. Hydrogen, the Simplest Atom (4)
14.2. Trends Across the Periodic Table. The Period 2 Elements (1)
14.3. Group 1A(1). The Alkali Metals (24)
14.4. Group 2A(2). The Alkaline Earth Metals (24)
14.5. Group 3A(13). The Boron Family (35)
14.6. Group 4A(14). The Carbon Family (23)
14.7. Group 5A(15). The Nitrogen Family (28)
14.8. Group 6A(16). The Oxygen Family (20)
14.9. Group 7A(17). The Halogens (20)
14.10. Group 8A(18). The Noble Gases (8)
14. Comprehensive Problems (8)
14. Follow-Up Problems
14. Chemical Connections
14. Test Bank (103)
14. Extra Problems (10)
14. WebAssign Answer Entry Tutorials

Chapter 15. Organic Compounds and the Atomic Properties of Carbon
15.1. The Special Nature of Carbon and the Characteristics of Organic Molecules (2)
15.2. The Structures and Classes of Hydrocarbons (91)
15.3. Some Important Classes of Organic Reactions (27)
15.4. Properties and Reactivities of Common Functional Groups (15)
15.5. The Monomer-Polymer Theme I. Synthetic Macromolecules
15.6. The Monomer-Polymer Theme II. Biological Macromolecules (11)
15. Comprehensive Problems (6)
15. Follow-Up Problems (7)
15. Chemical Connections
15. Test Bank (101)
15. Extra Problems (4)
15. WebAssign Answer Entry Tutorials

Chapter 16. Kinetics. Rates and Mechanisms of Chemical Reactions
16.1. Focusing on Reaction Rate
16.2. Expressing the Reaction Rate (2)
16.3. The Rate Law and Its Components (5)
16.4. Integrated Rate Laws. Concentration Changes over Time (43)
16.5. Theories of Chemical Kinetics (28)
16.6. Reaction Mechanisms. The Steps from Reactant to Product (20)
16.7. Catalysis. Speeding Up a Reaction (34)
16. Comprehensive Problems (27)
16. Follow-Up Problems (8)
16. Chemical Connections
16. Test Bank (74)
16. Extra Problems (2)
16. WebAssign Answer Entry Tutorials

Chapter 17. Equilibrium. The Extent of Chemical Reactions
17.1. The Equilibrium State and the Equilibrium Constant (16)
17.2. The Reaction Quotient and the Equilibrium Constant (12)
17.3. Expressing Equilibria with Pressure Terms. Relation Between Kc and Kp (13)
17.4. Comparing Q and K to Determine Reaction Direction (3)
17.5. How to Solve Equilibrium Problems (21)
17.6. Reaction Conditions and Equilibrium. Le Châtelier's Principle (25)
17. Comprehensive Problems (9)
17. Follow-Up Problems (14)
17. Chemical Connections
17. Test Bank (89)
17. Extra Problems (4)
17. WebAssign Answer Entry Tutorials

Chapter 18. Acid-Base Equilibria
18.1. Acids and Bases in Water (12)
18.2. Autoionization of Water and the pH Scale (36)
18.3. Proton Transfer and the Brønsted-Lowry Acid-Base Definition (25)
18.4. Solving Problems Involving Weak-Acid Equilibria (34)
18.5. Molecular Properties and Acid Strength (14)
18.6. Weak Bases and Their Relation to Weak Acids (11)
18.7. Acid-Base Properties of Salt Solutions (17)
18.8. Generalizing the Brønsted-Lowry Concept. The Leveling Effect
18.9. Electron-Pair Donation and the Lewis Acid-Base Definition (15)
18. Comprehensive Problems (26)
18. Follow-Up Problems (13)
18. Chemical Connections
18. Test Bank (91)
18. Extra Problems (3)
18. WebAssign Answer Entry Tutorials

Chapter 19. Ionic Equilibria in Aqueous Systems
19.1. Equilibria of Acid-Base Buffers (42)
19.2. Acid-Base Titration Curves (19)
19.3. Equilibria of Slightly Soluble Ionic Compounds (98)
19.4. Equilibria Involving Complex Ions (14)
19. Comprehensive Problems (28)
19. Follow-Up Problems (12)
19. Chemical Connections (1)
19. Test Bank (104)
19. Extra Problems (2)
19. WebAssign Answer Entry Tutorials

Chapter 20. Thermodynamics. Entropy, Free Energy, and the Direction of Chemical Reactions
20.1. The Second Law of Thermodynamics. Predicting Spontaneous Change (7)
20.2. Calculating the Change in Entropy of a Reaction (6)
20.3. Entropy, Free Energy, and Work (50)
20.4. Free Energy, Equilibrium, and Reaction Direction (9)
20. Comprehensive Problems (1)
20. Follow-Up Problems (7)
20. Chemical Connections
20. Test Bank (80)
20. Extra Problems
20. WebAssign Answer Entry Tutorials

Chapter 21. Electrochemistry. Chemical Change and Electrical Work
21.1. Redox Reactions and Electrochemical Cells (41)
21.2. Voltaic Cells. Using Spontaneous Reactions to Generate Electrical Energy (2)
21.3. Cell Potential. Output of a Voltaic Cell (6)
21.4. Free Energy and Electrical Work (36)
21.5. Electrochemical Processes in Batteries
21.6. Corrosion. An Environmental Voltaic Cell
21.7. Electrolytic Cells. Using Electrical Energy to Drive Nonspontaneous Reactions (12)
21. Comprehensive Problems (46)
21. Follow-Up Problems (10)
21. Chemical Connections
21. Test Bank (94)
21. Extra Problems (4)
21. WebAssign Answer Entry Tutorials

Chapter 22. The Elements in Nature and Industry
22.1. How the Elements Occur in Nature (2)
22.2. The Cycling of Elements Through the Environment (16)
22.3. Metallurgy. Extracting a Metal from Its Ore (33)
22.4. Tapping the Crust. Isolation and Uses of Selected Elements (23)
22.5. Chemical Manufacturing. Two Case Studies (9)
22. Comprehensive Problems (8)
22. Follow-Up Problems
22. Chemical Connections
22. Test Bank (45)
22. Extra Problems (1)
22. WebAssign Answer Entry Tutorials

Chapter 23. Transition Elements and Their Coordination Compounds
23.1. Properties of the Transition Elements (10)
23.2. The Inner Transition Elements (2)
23.3. Coordination Compounds (74)
23.4. Theoretical Basis for the Bonding and Properties of Complexes (8)
23. Comprehensive Problems
23. Follow-Up Problems (6)
23. Chemical Connections
23. Test Bank (79)
23. Extra Problems (8)
23. WebAssign Answer Entry Tutorials

Chapter 24. Nuclear Reactions and Their Applications
24.1. Radioactive Decay and Nuclear Stability (27)
24.2. The Kinetics of Radioactive Decay (26)
24.3. Nuclear Transmutation. Induced Changes in Nuclei (16)
24.4. Effects of Nuclear Radiation on Matter (36)
24.5. Applications of Radioisotopes
24.6. The Interconversion of Mass and Energy (2)
24.7. Application of Fission and Fusion (13)
24. Comprehensive Problems (6)
24. Follow-Up Problems (5)
24. Chemical Connections
24. Test Bank (80)
24. Extra Problems (4)
24. WebAssign Answer Entry Tutorials